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nitrosyl fluoride : ウィキペディア英語版
nitrosyl fluoride

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Nitrosyl fluoride, NOF, is a covalently bonded nitrosyl compound.
==Reactions==
NOF is a highly reactive fluorinating agent that converts many metals to their fluorides, releasing nitric oxide in the process:
:''n'' NOF + M → MF''n'' + ''n'' NO
NOF also fluorinates fluorides to form adducts that have a salt-like character, such as NOBF4.
Aqueous solutions of NOF are powerful solvents for metals, by a mechanism similar to that seen in aqua regia. Nitrosyl fluoride reacts with water to form nitrous acid, which then forms nitric acid:
:NOF + H2O → HNO2 + HF
:3 HNO2 → HNO3 + 2 NO + H2O
Nitrosyl fluoride can also convert alcohols to nitrites:
:ROH + NOF → RONO + HF
It has a bent molecular shape.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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